Cyclic compounds replaced by a condensed ring system

摘要

Compounds of formula I ** Formula ** where X1 is S or O; A is a group A1 or A2; where A1 is a group of the following formula: ** Formula ** where denotes the link to the aromatic ring of formula (I); and W is selected from O and S; and A2 is a group -C (R7a) (R7b) -N (R52) -C (= O) -R62 B1, B2, B3, B4 and B5 are independently selected from the group consisting of N and CR2, with the condition that at most one of B1, B2, B3, B4 and B5 is N; Rg1 and Rg2 together form a bridging group selected from -CH2CH2CH2-, -CH2CH2CH2CH2-, -CH2CH2O-, -OCH2CH2-, -CH2OCH2-, -OCH2O-, -CH2CH2S (O) p-, -S (O) pCH2CH2-, -CH2S (O) pCH2-, -S (O) pCH2S (O) p-, -OCH2S (O) p-, -S (O) pCH2O-, -OCH2CH2CH2-, -CH2CH2CH2O-, -CH2OCH2CH2-, -CH2CH2OCH2 -, -OCH2CH2O-, -OCH2OCH2-, -CH2OCH2O-, - S (O) pCH2CH2CH2-, -CH2CH2CH2S (O) p-, -CH2S (O) pCH2CH2-, -CH2CH2S (O) pCH2CH2-, -CH2CH2S (O ) pCH2-, - S (O) pCH2CH2S (O) p-, -S (O) pCH2S (O) pCH2-, -CH2S (O) pCH2S (O) p-, -S (O) pCH2CH2O-, -OCH2CH2S (O) p-, - S (O) pCH2OCH2-, -OCH2S (O) pCH2-, -CH2OCH2S (O) p and -CH2S (O) pCH2O-; where p is 0, 1 or 2 where the hydrogen atoms of the above groups can be replaced by one or more substituents selected from halogen, methyl, halogenated methyl, hydroxyl, methoxy and halogenated methoxy; and / or one or two CH2 groups from the above groups can be replaced by a C = O group; R1 is haloalkyl C1; each R2 is independently selected from the group consisting of hydrogen, halogen, C1-C2 haloalkoxy and C1-C2 haloalkyl; R3a and R3b, independently of each other, are selected from hydrogen and halogen; R7a and R7b, independently of each other, are selected from hydrogen, cyano, methyl and C1-haloalkyl; R51 and R52, independently of each other, are selected from the group consisting of hydrogen, C1-C3 alkyl, C2-C3 alkenyl, C2-C3 alkynyl, C1-C6 alkoxymethyl and CH2-CN; R61 is selected from the group consisting of hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkyl bearing one or two R81 radicals, C1-C6 haloalkyl bearing an R81 radical, C2-C6 alkenyl, C2 haloalkenyl C6, C2-C6 alkynyl, C3-C6 cycloalkyl which may be substituted with 1 or 2 CN substituents; C3-C6 halocycloalkyl; -N (R101a) R101b, - CH = NOR91, phenyl which may be substituted with 1, 2, 3, 4 or 5 R16 substituents, and a heterocyclic ring selected from rings E-1 to E-63 ** Formula ** where in rings E-1 to E-63 the zigzag line denotes the point of attachment to the rest of the molecule; k is 0, 1, 2, or 3; n is 0, 1 or 2; and R16 is as defined below; R62 is selected from the group consisting of hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkyl substituted by one or two R82 radicals, C1-C6 haloalkyl bearing a R82 radical, C2-C6 alkenyl, C2 haloalkenyl C6, C2-C6 alkynyl, C2-C6 haloalkynyl, C3-C6 cycloalkyl optionally bearing a CN substituent, C3-C6 halocycloalkyl, - N (R102a) R102b, -C (= O) N (R112a) R112b, -CH = NOR92, phenyl which is optionally substituted with 1, 2, 3, 4 or 5 R16 substituents; and a heterocyclic ring selected from the rings of formulas E-1 to E-63 as defined above; each R81 is independently selected from OH, CN, C3-C8 cycloalkyl optionally bearing a CN substituent or C1-haloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthiothio, alkylsulfinyl C1-C6, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, -C (= O) N (R101c) R101d, phenyl, optionally substituted with 1, 2, 3, 4 or 5 R16 substituents, and a heterocyclic ring selected from rings E-1 to E-63 as defined above; each R82 is independently selected from OH, CN, C3-C6 cycloalkyl optionally bearing a CN substituent or C1-haloalkyl, C3-C6 halocycloalkyl, C1-C6 alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthiothio, alkylsulfinyl C1-C6, C1-C6 haloalkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylsulfonyl, -C (= O) N (R102c) R102d, phenyl, optionally substituted with 1, 2, 3, 4 or 5 R16 substituents, and a heterocyclic ring selected from rings E-1 to E-63 as defined above; R91 and R92, independently of one another, are selected from hydrogen, C1-C6 alkyl, and C1-C6 haloalkyl; R101a, R102a, R102c and R112a, independently of each other, are selected from hydrogen and C1-C6 alkyl; R101b is selected from hydrogen, -C (= O) N (R14a)) R14b, phenyl, optionally substituted with 1, 2, 3, 4 or 5 R16 substituents; and a heterocyclic ring selected from rings of formulas E-1 to E-42 as defined above; R102b is selected from hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, CH2-CN, C2-C4 alkenyl, C2-C4 alkynyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkylmethyl, phenyl, optionally substituted with 1, 2, 3, 4 or 5 R16 substituents; and a heterocyclic ring selected from rings of formulas E-1 to E-42 as defined above; R101c is selected from the group consisting of hydrogen, C1-C6 alkyl, C2-C3 alkynyl, and CH2-CN; R101d is selected from the group consisting of hydrogen, C1-C6 alkyl, C2-C4 alkenyl, C2-C4 alkynyl, CH2-CN, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, halocycloalkylmethyl C3-C6, C1-C6 alkoxy, C1-C6 haloalkoxy, phenyl which is optionally substituted with 1, 2, 3, 4 or 5 substituents selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1- haloalkyl C4, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C2-C4 haloalkynyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C1-C4 alkoxy, C1-C4 alkylthio, and C1- haloalkylthio C4; and a heterocyclic ring selected from rings of formulas E-1 to E-63 as defined above; R102d and R112b independently of each other are selected from hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 haloalkynyl, C3-C6 cycloalkyl which optionally carries a CN substituent, C3-C6 halocycloalkyl, C3-C6 cycloalkylmethyl and C3-C6 halocycloalkylmethyl; R14a is selected from the group consisting of hydrogen and C1-C6 alkyl; R14b is selected from the group consisting of hydrogen, C1-C6 alkyl, C2-C4 alkenyl, C2-C4 alkynyl, CH2-CN, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, alkoxy C1-C4 and C1-C4 haloalkoxy; each R16 is independently selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 haloalkynyl, C3-C6 cycloalkyl , C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, halocycloalkyl-C3-C6-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-alkylsulfinyl , C1-C4 haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, C1-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkylaminocarbonyl, and di- (C1-C4 alkyl) -aminocarbonyl; or two R16s present on the same carbon atom of a saturated ring can together form = O or = S; or two R16s present on the same S or SO ring member of a heterocyclic ring can together form a group = N (C1-C6 alkyl), = NO (C1-C6 alkyl), = NN (H) (C1-C6 alkyl) ) o = NN (C1-C6 alkyl) 2; and N-oxides, stereoisomers and their agriculturally acceptable or veterinary salts.