首页> 外国专利> METHOD FOR MANUFACTURING NICKEL/COBALT MIXED SULFIDE FROM NICKEL OXIDE ORE BY WET SMELTING METHOD

METHOD FOR MANUFACTURING NICKEL/COBALT MIXED SULFIDE FROM NICKEL OXIDE ORE BY WET SMELTING METHOD

机译:湿法熔炼氧化镍矿中镍/钴混合硫化物的方法

摘要

Provided is a wet smelting method whereby the amount of nickel coprecipitated with impurities is reduced and nickel yield can be increased. The present invention provides a method for manufacturing a nickel/cobalt mixed sulfide, the method including: a leaching step S1 for performing sulfuric acid leaching of a nickel oxide ore slurry under high temperature and high pressure and obtaining a leached slurry; a solid/liquid separation step S2 for separating a leaching residue from the leached slurry and obtaining a leachate including an impurity together with nickel and coba a neutralization step S3 for sedimentation-separating a neutralized sediment formed by adjusting the pH of the leachate, and obtaining a neutral final liquid including nickel and coba a dezincification step S4 for separating zinc and other sulfides obtained by treating the neutral final liquid with hydrogen sulfide, and obtaining a dezincified final liquid; and a nickel recovery step S5 for recovering a mixed sulfide including nickel and cobalt obtained by treating the dezincified final liquid with hydrogen sulfide; wherein the Fe(III) concentration of the neutral final liquid is adjusted to 0.18 g/L or less.
机译:提供一种湿法熔融法,由此减少了与杂质共沉淀的镍的量,并且可以提高镍的产率。本发明提供了一种镍钴复合硫化物的制造方法,该方法包括:浸出步骤S1,用于在高温高压下对氧化镍矿浆进行硫酸浸出,得到浸出的浆;固/液分离步骤S2,用于从浸出的浆料中分离出浸出残余物,并获得包括杂质以及镍和钴的浸出液。中和步骤S3,用于沉降分离通过调节渗滤液的pH形成的中和的沉淀物,并获得包含镍和钴的中性最终液体;脱锌步骤S4,其用于分离锌和其他硫化物,所述锌和其他硫化物通过用硫化氢处理中性最终液体而获得,并获得脱锌的最终液体;镍回收步骤S5,用于回收将脱锌后的最终液用硫化氢处理而得到的包含镍和钴的混合硫化物。其中中性最终液体的Fe(III)浓度被调节为0.18g / L或更小。

著录项

  • 公开/公告号WO2020149122A1

    专利类型

  • 公开/公告日2020-07-23

    原文格式PDF

  • 申请/专利权人 SUMITOMO METAL MINING CO. LTD.;

    申请/专利号WO2019JP50726

  • 发明设计人 SUGINOHARA MAKOTO;SATO YOSHITERU;

    申请日2019-12-24

  • 分类号C22B23;C22B3/08;C22B3/22;C22B3/44;

  • 国家 WO

  • 入库时间 2022-08-21 11:10:08

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