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ULTRAVIOLET RAY-CURABLE SILICONE ADHESIVE AGENT COMPOSITION, AND METHOD FOR PRODUCING LAMINATE

机译:紫外线可固化硅酮胶黏剂组合物及其生产层压板的方法

摘要

An ultraviolet ray-curable silicone adhesive agent composition comprising (A) a polysiloxane represented by formula (1): (R1SiO3/2)a1(R13SiO1/2)b1(X1O1/2)c1 (wherein R1 represents a monovalent hydrocarbon group wherein a methyl group accounts for 20 mol% or more and an alkenyl group accounts for 0.1 to 50 mol%; X1 represents a hydrogen atom or the like; a1 represents 0.1 to 1; b1 represents 0 to 0.75; and c1 represents 0 to 0.1; and the requirement represented by the formula: a1+b1+c1 = 1 is satisfied), (B) a polysiloxane represented by formula (2): (R23SiO1/2)a2(R22SiO)b2 (wherein R2 represents a monovalent hydrocarbon group wherein a methyl group accounts for 20 mol% or more and an alkenyl group accounts for 0.01 to 25 mol%; a2 represents 0.001 to 0.67; b2 represents 0.33 to 0.999; and the requirement represented by the formula: a2+b2 = 1 is satisfied), (C) a hydrogen polysiloxane represented by formula (3): R3dHeSiO[(4-d-e)/2] (wherein R3 represents a monovalent hydrocarbon group; and d and e represent numerical values satisfying the requirements represented by the formulae: 0.7 ≦ d ≦ 2.5, 0.01 ≦ e ≦ 1.0 and 0.8 ≦ d+e ≦ 2.7) and (D) a platinum-group catalyst capable of being activated with light having a wavelength of 200 to 500 nm. The ultraviolet ray-curable silicone adhesive agent composition can provide a cured article having excellent adhesion force to an object of interest even when being cured under room temperature.
机译:紫外线固化型有机硅粘合剂组合物,其包含(A)由式(1)表示的聚硅氧烷:(R 1 SiO 3/2 a1 (R 1 3 SiO 1/2 b1 (X 1 O 1/2 c1 (其中R 1 表示一价烃基,其中甲基占20 mol%或更多,烯基基占0.1〜50mol%; X 1 表示氢原子等; a1表示0.1〜1; b1表示0〜0.75; c1表示0〜0.1;且要求为式(a1 + b1 + c1 = 1)。(B)式(2)表示的聚硅氧烷:(R 2 3 SiO 1 / 2 a2 (R 2 2 SiO) b2 (其中R 2 < / Sup>表示一价烃基,其中甲基占20摩尔%以上,烯基占0.01至25摩尔%; a 2表示0.001至0.67; b 2表示0.33至0.999; (a2 + b2 = 1)。(C)式(3)所示的氢聚硅氧烷:R 3 d H e SiO [(4-de)/ 2] (其中R 3 表示一价烃基; d和e表示满足要求的数值式(0.7≤d≤2.5、0.01≤e≤1.0和0.8≤d+e≤2.7)和(D)能够用波长200〜500nm的光活化的铂系催化剂。紫外线固化性有机硅粘合剂组合物即使在室温下固化也可以提供对目标物体具有优异的粘合力的固化物。

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