首页> 外国专利> Production of moldings from an inorganic-organic hybrid polymer with high resolution by means of 3D printing, moldings with high flexural strengths and elastic moduli and their use for dental purposes

Production of moldings from an inorganic-organic hybrid polymer with high resolution by means of 3D printing, moldings with high flexural strengths and elastic moduli and their use for dental purposes

机译:通过3D打印由高分辨率的无机-有机杂化聚合物生产模制品,具有高弯曲强度和弹性模量的模制品及其在牙科方面的用途

摘要

The invention relates to a method for producing a shaped body with the aid of a radiation-induced printing process according to the technique of the one-photon polymerization process, characterized in that the shaped body is produced by solidifying a liquid or viscous material which is a polysiloxane component which with hydrolytic condensation of one or more monomeric silanes with only two or three hydrolyzable groups and at least one organically polymerizable radical which is bonded to the silicon atom via carbon and was formed and contains an initiator and / or catalyst for the radiation-induced polymerization of the organically polymerizable radical , and- the solidification takes place in that light from a radiation source is directed onto an area of a surface of a substrate, a layer of the liquid or viscous material located there being exposed to the radiation of an orga African polymerization and is thereby solidified, whereupon further layers of the liquid or viscous material, which are each on the layer of the last solidified material, are solidified with the aid of this radiation source. The invention also relates to a shaped body based on an organically polymerized silica ( hetero) polycondensate, which was produced by organic polymerization of the polysiloxane component mentioned, with superior mechanical properties
机译:本发明涉及一种根据单光子聚合方法的技术借助于辐射诱导的印刷方法生产成型体的方法,其特征在于,成型体是通过将液态或粘性材料固化而制备的。一种聚硅氧烷组分,它与一种或多种仅具有两个或三个可水解基团的单体硅烷和至少一个可有机聚合的自由基发生水解缩合,该自由基通过碳与硅原子键合并形成,并包含引发剂和/或用于辐射的催化剂-引发有机可聚合基团的聚合反应,以及-固化过程是这样进行的:将来自辐射源的光引导到基材表面的区域上,位于该基材表面上的一层液体或粘性材料暴露于基材的辐射下。非洲高加索聚合反应,然后固化,随后液体或粘性材料的其他层借助于该辐射源,分别固化在最后固化的材料的层上的金属被固化。本发明还涉及基于有机聚合的二氧化硅(杂)缩聚物的成型体,其通过所述聚硅氧烷组分的有机聚合制备,具有优异的机械性能。

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