首页> 外国专利> PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE.

PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE.

机译:生产2,3,3,3-四氟戊烷的过程。

摘要

The present invention relates to a process for producing 2,3,3,3-tetrafluoropropene comprising the steps of: a) bringing into contact, in the gas phase, a compound of formula (I) CH (n + 2) (X ) m-CHp (X) (n + 1) -CX (3 + pm) where X independently represents F or Cl; n, m, p are independently of each other 0 or 1 with (n + m) = 0 or 1, (n + p) = 0 or 1 and (mp) = 0 or 1, at least one X being Cl, with hydrofluoric acid to obtain a product flow comprising 2,3,3,3-tetrafluoropropene, HCl and HF, b) cooling the product flow from the reactor of step a) to a temperature of 0 ° C. at 70 ° C, preferably at a temperature of 20 ° C to 50 ° C, c) distillation of the stream cooled in step b) to form a first stream comprising 2,3,3,3-tetrafluoropropene and HCl, and a second stream comprising HF, d) compression of the first stream obtained in step c) to form a first compressed stream, e) distillation of said first compressed stream obtained in step d) for a third stream comprising HCI and a fourth stream comprising 2,3,3,3-tetrafluoropropene, f) purification of said fourth stream obtained in step e), characterized in that step a) is carried out at a lower pressure 10 bara, preferably at a pressure of 2 to 8 bara, especially from 3 to 7 bara, more preferably from 5 to 7 bara.
机译:本发明涉及一种生产2,3,3,3-四氟丙烯的方法,该方法包括以下步骤:a)在气相中使式(I)的化合物CH(n + 2)(X)接触。 m-CHp(X)(n + 1)-CX(3 + pm),其中X独立地表示F或Cl; n,m,p彼此独立地为0或1,其中(n + m)= 0或1,(n + p)= 0或1且(mp)= 0或1,至少一个X为Cl,其中氢氟酸以获得包含2,3,3,3-四氟丙烯,HCl和HF的产物流,b)将步骤a)的反应器中的产物流在70°C,优选在70°C下冷却至0°C在20°C到50°C的温度下,c)蒸馏在步骤b)中冷却的物流以形成包含2,3,3,3-四氟丙烯和HCl的第一物流和包含HF的第二物流,d)压缩步骤c)中获得的第一物流的一部分,以形成第一压缩物流,e)蒸馏步骤d)中获得的所述第一压缩物流,以得到包含HCl的第三物流和包含2,3,3,3-四氟丙烯的第四物流, f)纯化步骤e)中获得的所述第四物流,其特征在于步骤a)在较低的10bara压力下,优选在2至8bara,特别是3至7bara,更优选从5bara的压力下进行。 5至7 bara。

著录项

  • 公开/公告号FR3064627B1

    专利类型

  • 公开/公告日2020-02-21

    原文格式PDF

  • 申请/专利权人 ARKEMA FRANCE;

    申请/专利号FR20170052579

  • 发明设计人 DEUR-BERT DOMINIQUE;WENDLINGER LAURENT;

    申请日2017-03-28

  • 分类号C07C17/20;C01B7/07;C07C17/25;C07C17/383;C07C21/18;

  • 国家 FR

  • 入库时间 2022-08-21 11:00:42

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