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Process for the rapid synthesis of an AFX-structural-type zeolite with a source of faujasite

机译:具有八面沸石来源的AFX结构型沸石的快速合成方法

摘要

The present invention relates to a process for the rapid synthesis of a zeolite with structure type AFX comprising at least: i) the mixture in aqueous medium, of a zeolite with structure type FAU having an SiO2 (FAU) / Al2O3 (FAU) molar ratio between 2.00 and 100, of a nitrogenous organic compound R, of at least one source of at least one alkali and / or alkaline earth metal M of valence n, with the following molar composition: (SiO2 (FAU )) / (Al2O3 (FAU)) between 2.00 and 100, H2O / (SiO2 (FAU)) between 1 and 100, R / (SiO2 (FAU)) between 0.01 and 0.6, M2 / nO / (SiO2 (FAU)) between 0.005 to 0.45, in which SiO2 (FAU) denotes the amount of SiO2 supplied by the FAU zeolite, and Al2O3 (FAU) denotes the amount of Al2O3 supplied by the FAU zeolite, until a homogeneous precursor gel is obtained; ii) the hydrothermal treatment of said precursor gel obtained at the end of step i) under autogenous pressure at a temperature between 120 ° C and 250 ° C, for 4 to 12 hours. Figure 1 to publish
机译:快速合成具有AFX结构类型的沸石的方法本发明涉及一种快速合成具有AFX结构类型的沸石的方法,该方法至少包括:i)在水介质中的具有SiO 2(FAU)/ Al 2 O 3(FAU)摩尔比的FAU结构类型的沸石的混合物。 2.00至100之间的一种含氮有机化合物R,至少一种价数为n的碱金属和/或碱土金属M的至少一种来源,具有以下摩尔组成:(SiO2(FAU))/(Al2O3(FAU ))在2.00和100之间,H2O /(SiO2(FAU))在1和100之间,R /(SiO2(FAU))在0.01和0.6之间,M2 / nO /(SiO2(FAU))在0.005至0.45之间,其中SiO 2(FAU)表示由FAU沸石提供的SiO 2的量,Al 2 O 3(FAU)表示由FAU沸石提供的直至得到均质的前体凝胶的Al 2 O 3的量。 ii)在自生压力下在120℃至250℃之间的温度下对在步骤i)结束时获得的所述前体凝胶进行水热处理4至12小时。图1发布

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