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Mercaptotriazole-based drag-reducing agent for gas transmission pipelines and preparation method therefor

机译:巯基三唑类输气管道减阻剂及其制备方法

摘要

The present invention provides a mercaptotriazole-based drag-reducing agent for gas pipelines and its preparation method. The drag-reducing agent is prepared by the following steps: producing 1,3-diaminothiourea from hydrazine hydrate and carbon disulfide in a mass ratio of 3:1 to 4:1 under the action of Catalyst I; producing a dithiocarbohydrazone from the condensation reaction of 1,3-diaminothiourea and an aromatic aldehyde in a mass ratio of 1:1 to 1:1.5; producing a mercaptotriazole compound from the dithiocarbohydrazone and an aromatic ester in a mass ratio of 1:1 to 1:3 under the action of Catalyst II; dissolving the mercaptotriazole compound in acetone, adding phosphoric acid or phosphate(s) thereto, and thoroughly mixing them to obtain the target product. The present invention has simple operation and mild reaction conditions and is suitable for online atomization and injection, and the raw materials thereof are available from direct sources.
机译:本发明提供了一种用于天然气管道的巯基三唑类减阻剂及其制备方法。减阻剂是通过以下步骤制备的:在催化剂I的作用下,由水合肼和二硫化碳以3∶1至4∶1的质量比制备1,3-二氨基硫脲。由1,3-二氨基硫脲与芳香族醛的缩合反应,以1:1〜1:1.5的质量比生成二硫代碳hydr。在催化剂II的作用下,由二硫代碳hydr与芳香族酯以1:1至1:3的质量比制备巯基三唑化合物;将巯基三唑化合物溶解在丙酮中,向其中加入磷酸或磷酸盐,并将它们充分混合以获得目标产物。本发明操作简单,反应条件温和,适用于在线雾化和注射,其原料可直接获得。

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