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PROCÉDÉ DE TRAITEMENT DE PARTICULES DE POLYOLÉFINE OBTENUES PAR POLYMÉRISATION EN PHASE GAZEUSE
PROCÉDÉ DE TRAITEMENT DE PARTICULES DE POLYOLÉFINE OBTENUES PAR POLYMÉRISATION EN PHASE GAZEUSE
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摘要
Process for treating polyolefin particles obtained by gas-phase polymerization of one or more olefins in the presence of a polymerization catalyst system and a C 3 -C 5 alkane as polymerization diluent in a gas-phase polymerization reactor, the process comprising the steps of a) discharging the polyolefin particles continuously or discontinuously from the gas-phase polymerization reactor and transferring the particles to a first degassing vessel; b) contacting therein the polyolefin particles with a gaseous stream comprising at least 85 mol-% of C 3 -C 5 alkane while the polyolefin particles have an average residence time in the first degassing vessel of from 5 minutes to 5 hours; c) transferring the polyolefin particles to a second degassing vessel; d) contacting therein the polyolefin particles with a stream comprising nitrogen and steam while the polyolefin particles have an average residence time in the second degassing vessel of from 5 minutes to 2 hours; e) transferring the polyolefin particles to a third degassing vessel; f) contacting therein the polyolefin particles with a stream of nitrogen while the polyolefin particles have an average residence time in the third degassing vessel of from 5 minutes to 8 hours, and processes for preparing polyolefin polymers by gas-phase polymerization of one or more olefins in the presence of a polymerization catalyst system and a C 3 -C 5 alkane as polymerization diluent in a gas-phase polymerization reactor, wherein the obtained polyolefin particles are subjected to such a treating process.
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