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Advances in heterogeneous photocatalytic degradation of phenols and dyes in wastewater : a review

机译:废水中酚类和染料的非均相光催化降解研究进展

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摘要

The heterogeneous photocatalytic water purification process has gained wide attention due to its effectiveness in degrading and mineralizing the recalcitrant organic compounds as well as the possibility of utilizing the solar UV and visible light spectrum. This paper aims to review and summarize the recently published works in the field of photocatalytic oxidation of toxic organic compounds such as phenols and dyes, predominant in waste water effluent. In this review, the effects of various operating parameters on the photocatalytic degradation of phenols and dyes are presented. Recent findings suggested that different parameters, such as type of photocatalyst and composition, light intensity, initial substrate concentration, amount of catalyst, pH of the reaction medium, ionic components in water, solvent types, oxidizing agents/electron acceptors, mode of catalyst application, and calcinations temperature can play an important role on the photocatlytic degradation of organic compounds in water environment. Extensive research has focused on the enhancement of photocatalysis by modification of TiO2 employing metal, non-metal and ion doping. Recent advances in TiO2 photocatalysis for the degradation of various phenols and dyes are also highlighted in this review.
机译:异质光催化水净化工艺因其有效降解难矿化有机化合物并使之矿化以及利用太阳紫外线和可见光谱的可能性而受到广泛关注。本文旨在回顾和总结最近发表的有关光催化氧化有毒有机化合物(例如废水中的主要酚类和染料)领域的工作。在这篇综述中,提出了各种操作参数对苯酚和染料的光催化降解的影响。最近的发现表明不同的参数,例如光催化剂的类型和组成,光强度,初始底物浓度,催化剂的量,反应介质的pH,水中的离子成分,溶剂类型,氧化剂/电子受体,催化剂的应用方式煅烧温度对水环境中有机化合物的光催化降解起着重要作用。广泛的研究集中在通过使用金属,非金属和离子掺杂改性TiO2来增强光催化作用。这篇综述还重点介绍了TiO2光催化降解各种酚和染料的最新进展。

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