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Shear banding in soft glassy materials.

机译:柔软玻璃质材料的剪切带。

摘要

Many soft materials, including microgels, dense colloidal emulsions, star polymers, dense packings of multilamellar vesicles, and textured morphologies of liquid crystals, share the basic 'glassy' features of structural disorder and metastability. These in turn give rise to several notable features in the low frequency shear rheology (deformation and flow properties) of these materials: in particular, the existence of a yield stress below which the material behaves like a solid, and above which it flows like a liquid. In the last decade, intense experimental activity has also revealed that these materials often display a phenomenon known as shear banding, in which the flow profile across the shear cell exhibits macroscopic bands of different viscosity. Two distinct classes of yield stress fluid have been identified: those in which the shear bands apparently persist permanently (for as long as the flow remains applied), and those in which banding arises only transiently during a process in which a steady flowing state is established out of an initial rest state (for example, in a shear startup or step stress experiment). Despite being technically transient, such bands may in practice persist for a very long time and so be mistaken for the true steady state response of the material in experimental practice. After surveying the motivating experimental data, we describe recent progress in addressing it theoretically, using the soft glassy rheology model and a simple fluidity model. We also briefly place these theoretical approaches in the context of others in the literature, including elasto-plastic models, shear transformation zone theories, and molecular dynamics simulations. We discuss finally some challenges that remain open to theory and experiment alike.
机译:许多软质材料,包括微凝胶,致密的胶体乳液,星形聚合物,多层囊泡的致密堆积以及液晶的织构形态,均具有结构紊乱和亚稳性的基本“玻璃状”特征。这些又在这些材料的低频剪切流变学(变形和流动特性)中产生了几个显着的特征:特别是存在屈服应力,在该屈服应力以下,材料表现为固体,在其之上流动,则表现为固体。液体。在过去的十年中,激烈的实验活动还揭示了这些材料通常表现出一种称为剪切带的现象,其中穿过剪切单元的流动曲线显示出不同粘度的宏观带。已经确定了两种截然不同的屈服应力流体类别:一种是剪切带明显永久地保持(只要施加流动就一直存在),另一种是在建立稳定流动状态的过程中仅暂时出现带的那些超出初始静止状态(例如,在剪切启动或阶跃应力实验中)。尽管在技术上是瞬态的,但这种带在实践中可能会持续很长时间,因此在实验实践中会误认为该材料的真实稳态响应。在调查了具有启发性的实验数据后,我们使用软玻璃流变模型和简单流动性模型,从理论上描述了解决该问题的最新进展。我们还将这些理论方法简要地放在其他文献的上下文中,包括弹塑性模型,剪切转变区理论和分子动力学模拟。最后,我们讨论一些仍然面临理论和实验挑战的挑战。

著录项

  • 作者

    Fielding Suzanne M.;

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  • 年度 2014
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  • 原文格式 PDF
  • 正文语种 {"code":"en","name":"English","id":9}
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