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Effect of Heating Time and Temperature on the Chemical Characteristics of Biochar from Poultry Manure

机译:加热时间和温度对家禽粪便生物炭化学特性的影响

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摘要

Poultry manure (PM) chars were obtained at different temperatures and charring times. Chemical−physicaludcharacterization of the different PM chars was conducted by cross-polarization magic angle spinning (CPMAS) 13C NMRudspectroscopy and thermal analysis. CPMAS 13C NMR spectra showed that the chemical composition of PM char is dependent onudproduction temperature rather than on production duration. Aromatic and alkyl domains in the PM chars obtained at the lowestudtemperatures remained unchanged at all heating times applied for their production. The PM char obtained at the highestudtemperature consisted only of aromatic structures having chemical nature that also appeared invariant with heating time.udThermogravimetry revealed differences in the thermo-oxidative stability of the aromatic domains in the different PM chars. TheudPM char produced at the highest temperature appeared less stable than those produced at the lowest temperatures. Thisuddifference was explained by a protective effect of the alkyl groups, which are still present in chars formed at lower temperature.udThe analysis of the chemical and physicochemical character of poultry manure chars produced at different temperatures canudincrease understanding of the role of these materials in the properties and behavior of char-amended soils.
机译:在不同温度和炭化时间下获得家禽粪便(PM)炭。通过交叉极化幻角旋转(CPMAS)13C NMR udspectroscopy和热分析进行了不同PM炭的化学-物理表征。 CPMAS 13C NMR光谱表明,PM炭的化学成分取决于生产温度而不是生产时间。在最低/低温下获得的PM炭中的芳族和烷基结构域在用于其生产的所有加热时间均保持不变。在最高温度下获得的PM炭仅由具有化学性质的芳族结构组成,该结构也随加热时间而变化。在热重分析中发现,不同PM炭中芳族结构域的热氧化稳定性存在差异。在最高温度下产生的 udPM炭表现出比在最低温度下产生的 udPM炭不稳定。这种差异是由烷基的保护作用所解释的,这些烷基仍存在于较低温度下的炭中。 ud对不同温度下生产的家禽粪便炭的化学和理化特性进行分析可以加深对家禽粪便的作用的了解。这些材料在炭化土壤的性质和性能方面。

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