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Biodiesel production from moringa oleifera seeds using heterogeneous acid and alkali catalyst

机译:使用多相酸和碱催化剂从辣木种子生产生物柴油

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摘要

Due to the increasing energy demand and pollution problems caused by the use of fossil fuels, it has become necessary to develop alternative fuels as well as renewable sources of energy. The use of biodiesel as a substitute for conventional diesel has been of great interest. This is because biodiesel is biodegradable, non-toxic, renewable, and has low emission of carbon oxide, sulphur dioxide, particulates and hydrocarbons as compared to conventional diesel. Therefore, this study is conducted to investigate the possible production of biodiesel by using Moringa oleifera seeds oil through heterogeneous (acid and alkali) catalyst process. Moringa oleifera seeds oil can be used for biodiesel production by transesterification using calcium oxide (CaO) as an alkaline catalyst followed by esterification by using ferric sulphate catalyst. A sample of 50 mL oil was poured into the 3-neck round-bottom glass flask. Carefully, the methanol was poured into the oil with ratio 6:1, 12:1 and 18:1 for both alkali-catalyzed transesterification and acid-catalyzed esterification process. The catalyst concentrations, time reaction, agitation speed and the temperatures are fixed at 1wt%, 90 minutes, 200 rpm and 70 oC, respectively. As a result, the methyl esters (biodiesel) produced from Moringa oleifera seeds oil exhibits a high yield which is 48 mL (96%) and 45 mL (90%) for both alkali-catalyzed transesterification and acid-catalyzed esterification process by using methanol to oil ratio of 18:1, and catalyst concentrations, time reaction, agitation speed and the temperatures are fixed at 1wt%, 90 minutes, 200 rpm and 70 oC, respectively. As a conclusion, biodiesel can be produced from Moringa oleifera seeds oil as an alternative fuels as well as renewable sources of energy for future use
机译:由于使用化石燃料引起的能源需求增加和污染问题,发展替代燃料以及可再生能源已成为必要。使用生物柴油代替常规柴油引起了极大的兴趣。这是因为与常规柴油相比,生物柴油是可生物降解的,无毒的,可再生的,并且二氧化碳,二氧化硫,颗粒物和碳氢化合物的排放量低。因此,本研究旨在研究辣木籽油通过非均相(酸和碱)催化剂工艺生产生物柴油的可能性。辣木籽油可通过使用氧化钙(CaO)作为碱性催化剂进行酯交换反应,然后通过使用硫酸铁催化剂进行酯化反应来用于生物柴油生产。将50 mL油的样品倒入3颈圆底玻璃烧瓶中。小心地,将甲醇以6:1、12:1和18:1的比例倒入油中,以进行碱催化的酯交换反应和酸催化的酯化过程。催化剂浓度,时间反应,搅拌速度和温度分别固定在1wt%,90分钟,200 rpm和70 oC。结果,由辣木种子油生产的甲酯(生物柴油)在使用甲醇进行碱催化的酯交换反应和酸催化的酯化过程中均显示出高产量,分别为48 mL(96%)和45 mL(90%)。与油的比例为18:1,催化剂浓度,时间反应,搅拌速度和温度分别固定为1wt%,90分钟,200 rpm和70 oC。总之,可以从辣木籽油中生产生物柴油,作为替代燃料以及可再生能源,以备将来使用。

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    Aqilah Yahya;

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  • 年度 2013
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