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A Quantitative Tunneling/Desorption Model for the Exchange Current at the Porous Electrode/Beta - Alumina/Alkali Metal Gas Three Phase Zone at 700-1300K

机译：多孔电极/β - 氧化铝/碱金属气体三相区700-1300K交换电流的定量隧穿/解吸模型

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摘要

The exchange current observed at porous metal electrodes on sodium or potassium beta -alumina solid electrolytes in alkali metal vapor is quantitatively modeled with a multi-step process with good agreement with experimental results.

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作者
Williams, R. M.; Ryan, M. A.; Saipetch, C.; LeDuc, H. G.;
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年度 1996
页码 1-30
总页数 30
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
ALKALI METALS; ALUMINUM OXIDES; DESORPTION; ELECTRODES; ELECTRON TRANSFER; METAL VAPORS; POROSITY; POTASSIUM; SODIUM; SOLID ELECTROLYTES; VAPOR PHASES; electron transfer; exchange current metal electrodes alkali metal vapor electrochemical reactions;

机译：aLKaLI mETaLs;铝氧化物;解吸;电极，电子转移;金属蒸气;孔隙度;钾;钠;固体电解质;蒸气相;电子转移;交换电流金属电极碱金属蒸气电化学反应;

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1. Hydrogen transport through LaNi4.7Al0.3Hx porous electrode in the coexistence of two hydride phases (alpha- and beta-phases): current transient analysis [J] . Yang TH., Pyun SI. Electrochimica Acta . 1998,第5a6期

机译：氢通过LaNi4.7Al0.3Hx多孔电极在两个氢化物相（α相和β相）共存时的电流迁移：电流瞬态分析
2. Investigation of the non-isothermal water desorption on alkali-metal cation-exchanged X-type zeolites: a temperature-programmed diffuse reflection infrared Fourier transform spectroscopic (TP-DRIFTS) study [J] . Beta IA., Hunger B., Bohlig H. Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems . 2000,第1a2期

机译：碱金属阳离子交换的X型沸石在非等温水中的解吸研究：程序升温扩散反射红外傅里叶变换光谱（TP-DRIFTS）研究
3. Effect and role of alkali metals added to cobalt ion-exchanged X and Y zeolite catalysts in the gas-phase catalytic oxidation of benzyl alcohol [J] . Seiki T., Nakato A., Nishiyama S., Physical chemistry chemical physics: PCCP . 2003,第17期

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4. A QUANTITATIVE MODEL FOR THE EXCHANGE CURRENT OF POROUS MOLYBDENUM ELECTRODES ON SODIUM BETA"-ALUMINA IN SODIUM VAPOR [C] . Roger M. Williams, Margaret A. Ryan, Henry LeDuc, Intersociety Energy Conversion Engineering Conference . 1998

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6. Single Alkali Metal Ion-Activated Porous Carbon With Heteroatom Doping for Supercapacitor Electrode [O] . Changshui Wang 2020

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7. Ordered Porous Alumina Geometries and Surface Metals for Surface-Assisted Laser Desorption/Ionization of Biomolecules: Possible Mechanistic Implications of Metal Surface Melting [O] . -1

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8. A Quantitative Model for the Exchange Current of Porous Molybdenum Electrodes on Sodium Beta-Alumina in Sodium Vapor [R] . Williams, R. M., Ryan, M. A., LeDuc, H., 1998

机译：多孔钼电极在钠蒸气中钠 - 氧化铝交换电流的定量模型

A Quantitative Tunneling/Desorption Model for the Exchange Current at the Porous Electrode/Beta - Alumina/Alkali Metal Gas Three Phase Zone at 700-1300K

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