Inelastic Neutron Scattering Measurements of Phonon DispersionRelations inAndalusite and Sillimanite, Al 2 SiO 5

摘要

This paper reports inelastic neutron scattering (INS) measurements of the phonondispersion relations of the aluminium silicate minerals andalusite and sillimanite, Al2SiO5. The single crystal INS measurements were undertaken using the Triple-axis-spectrometer at the Dhruva reactor, Trombay for andalusite and at the Oak Ridge National Laboratory, U.S.A. for sillimanite. The phonon dispersion relations (up to 50 meV) along various high symmetry directions have been measured and have been analyzed on the basis of lattice dynamics shell model calculations. The calculated structure factors based on the model calculations were used as guides for planning these single crystal measurements and were used to identify regions in reciprocal space with large cross-sections. The calculated structure factors have been very useful in the planning, execution and analysis of the experimental data. The calculated phonon dispersion relations are found to be in good agreement with the measured data.