Synthesis, Chemistry and Catalytic Activity of Complexes of Lanthanide and Actinide Metals in Unusual Oxidation States and Coordination Environments. Progress Report for Period February 1, 1980-January 31, 1981

摘要

Investigations are being conducted on two classes of lanthanide compounds: metal vapor co-condensation reactions with unsaturated hydrocarbons and homoleptic and heteroleptic alkyl lanthanide complexes. Three models have been considered for the interaction of erbium atoms with 3-hexyne. The structure of the heteroleptic alkynide ((C sub 5 H sub 5 ) sub 2 ErC triple bond CCMe sub 3 ) sub 2 was studied. Some new organolanthanides have been prepared. (ERA citation 06:008014)