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Dioxododecaisopropoxytetratungsten. Oxygen Atom Abstraction from Acetone in Reactions with Hexaisopropoxyditungsten (M=M)

机译：Dioxododecaisopropoxytetratungsten。用六异丙氧基二苯醚（m = m）反应得到丙酮中的氧原子提取

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Hexaisopropoxyditungsten (W2(OPri)6(py)2) (M-M Triple bond) and acetone (1 equiv) react in hydrocarbon solvents and ambient temperatures to yield tetramethylethylene and Dioxododecaisopropxytetratungsten (W4O2(OPri)12) which is shown, by x-ray study, to be an unusual cluster type in which the 8 electrons available for M-M bonding are partitioned to a M-M triple and M-M single bond.

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Blatchford, T. P.; Chisholm, M. H.; Folting, K.; Huffman, J. C.;
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年度 1984
页码 p.1-9
总页数 9
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Tungsten; Acetones; Oxidation reduction reactions; Metal metal bonds; Alkoxy radicals; Clustering; Methylenes; Methyl radicals; Hydrocarbons; Solvents; Oxygen; Atoms;

机译：钨;丙酮;氧化还原反应;金属金属键;烷氧基;聚集;亚甲基;甲基;碳氢化合物;溶剂;氧;原子;

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1. Competitive hydrogen-atom abstraction versus oxygen-atom and electron transfers in gas-phase reactions of [X_4O_(10)]~+ (X = P, V) with C_2H_4 [J] . Dietl N., Engeser M., Schwarz H. Chemistry: A European journal . 2010,第15期

机译：[X_4O_（10）]〜+（X = P，V）与C_2H_4气相反应中氢原子竞争与氧原子和电子转移的竞争
2. Competitive hydrogen-atom abstraction versus oxygen-atom and electron transfers in gas-phase reactions of [X_4O_(10)]~+ (X = P, V) with C_2H_4 [J] . Dietl N., Engeser M., Schwarz H. Chemistry: A European journal . 2010,第15期

机译：[X_4O_（10）]〜+（X = P，V）与C_2H_4气相反应中氢原子竞争与氧原子和电子转移的竞争
3. Competitive Hydrogen-Atom Abstraction versus Oxygen-Atom and Electron Transfers in Gas-Phase Reactions of [X₄O₁₀].+ (X=P, V) with C₂H₄ [J] . Nicolas Dietl Dipl.-Chem., Marianne Engeser Dr., Helmut Schwarz Prof. Dr. Chemistry - A European Journal . 2010,第15期

机译：[X _{4 O _{10 ] 。+ 的气相反应中竞争性氢原子提取与氧原子和电子转移的关系（X = P，V）和C _{2 H ₄}}}
4. Computational Studies on the Reactions of Indenyl Radical with Oxygen Atom and Molecular Oxygen [C] . TSUCHIYA Kentaro, OGUMA Mitsuharu 日本化学会春季年会講演予稿集 . 2018

机译：茚基与氧原子和分子氧反应的计算研究
5. METAL ATOM REACTIVITY PATTERNS: THE REACTIONS OF METAL ATOMS WITH ACETONE, ZIRCONIUM ATOMS WITH ALKYLBENZENES, AND PLATINUM ATOMS AS ACTIVE SITES IN HETEROGENEOUS CATALYSTS (ELECTROMOTIVE FORCE, HYDROGENATION, ARENES, OLEFINS) [D] . ROSS, JEFFREY SCOTT 1986

机译：金属原子反应性模式：非均相催化剂中金属原子与丙酮，锆原子与烷基苯和铂原子作为活性位点的反应（电势，加氢，芳烃，烯烃）
6. Correlation of Hydrogen-Atom Abstraction Reaction Efficiencies for Aryl Radicals with their Vertical Electron Affinities and the Vertical Ionization Energies of the Hydrogen Atom Donors [O] . Linhong Jing, John J. Nash, Hilkka I. Kenttämaa -1

机译：芳基自由基的氢原子抽象反应效率与其垂直电子亲和力和氢原子给体的垂直电离能的相关性
7. Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane [O] . Pandit, Shubhrangshu, Hornung, Balazs, Dunning, Greg, 2017

机译：正戊烷在Cl原子反应中的主要H.原子与次要H原子抽象
8. Dioxododecaisopropoxytetratungsten. Oxygen Atom Abstraction from Acetone in Reactions with Hexaisopropoxyditungsten (M=M). [R] . Blatchford, T. P., Chisholm, M. H., Folting, K., 1984

机译：Dioxododecaisopropoxytetratungsten。用六异丙氧基二苯醚（m = m）与丙酮反应得到氧原子。

Dioxododecaisopropoxytetratungsten. Oxygen Atom Abstraction from Acetone in Reactions with Hexaisopropoxyditungsten (M=M)

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