Time-Resolved Resonance Raman Spectra of Polypyridyl Complexes of Ruthenium(II)

摘要

Time-resolved resonance Raman (TR3) spectroscopy has recently evolved as a powerful tool for the investigation of the dynamics and structures of a variety of of reactive intermediates electronic excited states, biological systems, and enzyme- substrate complexes. In this communication we report the TR3 spectra of three ruthenium complexes of special importance because of their binding ability to nucleic acids, because of their success as chiral probes, and because of their potential to serve as models for the interaction of metal ions with nucleic acids.