Facile Synthesis of Various 1-Azabicyclon.4.0alkanes via Beckmann Rearrangement/Allylsilane Cyclization

摘要

The carbon-carbon bond formation by the reaction of allylsilanes with electrophiles has been widely used in organic synthesis. Particulary, intramolecular cyclization of allysilanes bearing an electrophilic terminus has an extensive application for the highly regio- and stereo-selective synthesis of various ring compounds.