Extraction of Pd(_(_(_(II)))), Rh(_(_(_(III)))) and Ru(_(_(_(III)))) from HNO_3 aqueous solution to betainium bis- (trifluoromethanesulfonyl)imide ionic liquid

Kotoe Sasaki; Koichiro Takao; Tomoya SuzukiTakahiro MoriTsuyoshi AraiYasuhisa Ikeda

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Extraction of Pd(_(_(_(II)))), Rh(_(_(_(III)))) and Ru(_(_(_(III)))) from HNO_3 aqueous solution to betainium bis- (trifluoromethanesulfonyl)imide ionic liquid

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Extraction of Pd(_(_(_(II)))), Rh(_(_(_(III)))) and Ru(_(_(_(III)))) from HNO_3 aqueous solution to betainium bis- (trifluoromethanesulfonyl)imide ionic liquid

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摘要

Extraction efficiencies of Pd(_(_(_(II)))), Rh(_(_(_(III)))), and Ru(_(_(_(III)))) from HNO_3(aq) to HbetTf_2N were demonstrated, i.e., Pd(_(_(_(II)))) is the most extractable, Rh(_(_(_(III)))) is medium extractable, and Ru(_(_(_(III)))) is the least extractable. The extraction seems to proceed through coordination of betaine to the metal ions and the cation exchange of the formed complex with H~+.

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来源
《Dalton transactions: An international journal of inorganic chemistry 》 |2014年第15期| 5648-5651| 共4页
作者
Kotoe Sasaki; Koichiro Takao; Tomoya SuzukiTakahiro MoriTsuyoshi AraiYasuhisa Ikeda;
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作者单位

Department of Materials Science, Shibaura Institute of Technology, 3-7-5, Toyosu, Koto-ku, 135-8548 Tokyo, Japan;

Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, 152-8550 Tokyo, Japan;

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原文格式 PDF
正文语种英语
中图分类化学 ; 无机化学 ;
关键词
least extractable; cation exchange; formed complex;

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Extraction of Pd(_(_(_(II)))), Rh(_(_(_(III)))) and Ru(_(_(_(III)))) from HNO_3 aqueous solution to betainium bis- (trifluoromethanesulfonyl)imide ionic liquid

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