Morphology and Crystallization Behavior of Nylon 6-Clay/Neat Nylon 6 Bicomponent Nanocomposite Fibers

摘要

Nylon 6-clay hybrid/neat nylon 6, sheath/core bicomponent nanocomposite fibers containing 4 wt of clay in sheath section, were melt spun at different take-up speeds. Their molecular orientation and crystalline structure were compared to those of neat nylon 6 fibers. Moreover, the morphology of the bicomponent fibers and dispersion of clay within the fibers were analyzed using scanning electron microscopy and transmission electron microscopy (TEM), respectively. Birefringence measurements showed that the orientation development in sheath part was reasonably high while core part showed negligibly low birefringence. Results of differential scanning calorimetry showed that crystallinity of bicomponent fibers was lower than that of neat nylon 6 fibers. The peaks of γ-crystalline form were observed in the wide-angle X-ray diffraction of bicomponent and neat nylon 6 fibers in the whole take-up speed, while α-crystalline form started to appear at high speeds in bicomponent fibers. TEM micrographs revealed that the clay platelets were individually and evenly dispersed in the nylon 6 matrix. The neat nylon 6 fibers had a smooth surface while striped pattern was observed on the surface of bicomponent fibers containing clay. This was speculated to be due to thermal shrinkage of the core part after solidification of the sheath part in the spin-line.