Structural and high-field magnetic properties of Laves phase RFe2-H hydrides

摘要

The crystal structure and magnetic properties of the multicomponent compounds (Tb1-xYx)(0.8)Sm0.2Fe2Hz (x = 0, 0.2, 0.4, 0.6, 0.8, 1; z = 0 and 3.7) are investigated. The compounds crystallize in the MgCu2 type of structure. While the parent compounds Tb0.8Sm0.2Fe2 and Y0.8Sm0.2Fe2 are single phase, we detect 5-8 of a second phase with a crystal structure of the PuNi3 type (space group R3m) in the alloys with 0.2 LE; x < 0.8. Hydrogen absorption does not change the space group of the (Tb,Y,Sm)Fe-2 compounds but boosts significantly the lattice parameter a. A large volume change of UDelta;V/V SIM; 28 upon hydrogen absorption is observed. By applying high magnetic fields up to 58 T, we observed rotations of the magnetic sublattices and hence we were able to determine the critical transition fields, H, from the ferrimagnetic to the ferromagnetic state and the inter-sublattice exchange parameter lambda. The magnetic compensation occurs at x AP; 0.6 and 0.2 in (Tb1-xYx)(0.8)Sm0.2Fe2Hz at z = 0 and 3.7, respectively. While maintaining the collinear magnetic structure, the phenomenon of compensation in hydrides should be observed at x AP; 0.4.