Curve crossing problem with Gaussian type coupling: Analytically solvable model

摘要

We give a general method for finding an exact analytical solution for the two state curve crossing problem. The solution requires the knowledge of the Green's function for the motion on the uncoupled potentials. We use the method to find the solution of the problem in the case of parabolic potentials coupled by Gaussian interaction. Our method is applied to this model system to calculate the effect of curve crossing on the electronic absorption spectrum and the resonance Raman excitation profile.