A method to prepare well-aligned β-Na _(0.24)V _2O _5 nanowires (NWs) involves the deposition of a vanadium oxide complex onto a substrate via gaseous transport, followed by a reaction between the complex and a sodium cation (Na ~+) precursor coated on the substrate. Techniques to investigate the composition, crystallinity, and morphology of products as prepared include ICP-AES, X-ray powder diffraction (PXRD), SEM/transmission electron microscope (TEM), and XPS. PXRD patterns and images from a TEM confirm the single-crystalline nature of β-Na _(0.24)V _2O _5 NWs, which grow along direction 1 0 0. Factors affecting the amount of deposited material and morphology were tested. On varying the reaction conditions, the length of the β-Na _(0.24)V _2O _5 wires is controlled in a range of 5-25 lm. A mechanism of formation is proposed. According to measurements of field emission, the turn-on field is 7.8 V/lm, and the maximum emission current density of 4.66 mA/cm ~2 occurs at field 11 V/μm. This method is applicable to grow other tertiary metal oxide nanostructures on glass substrate.
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