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The analysis of drag reduction in Kuwaiti crude oil samples using surfactants and polyacrylamide

机译:使用表面活性剂和聚丙烯酰胺对科威特原油样品进行减阻分析

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摘要

The rheological characteristics of Kuwait crude oil samples were studied as a function of the American Petroleum Institute gravity(API),drag reduction material and concentration,isothermal and nonisothermal conditions,and mixer speed and frequency.Accurate measurements and analyses of rheological characteristics are important to determine the effect of a drag reduction agent and ambient conditions on the crude oil flow characteristics and required pumping power.Three crude oil samples obtained from different wells with API values of 14.81(crude A),16.33(crude B)and 14.09(crude C)were used in the experiments.Various polyacrylamide(PAM)concentrations were used to assess the effect on the rheological properties of the three crude oil samples.The disruption of wax crystal formation and the changes in loss modulus(G"),viscosity and strain were measured under isothermal and nonisothermal conditions.The PAM performance was compared with that of five surfactants,namely poly(sodium 4-styrenesulfonate)(PSSS),sodium dodecyl sulfate(SDS),cetyltrimethylammonium bromide(CTAB),hexadecylphosphocholine(HTPC),and CHP,which is an equal molar ratio mixture of PSSS,CTAB and HTPC.For a surfactant concentration of 70 ppm,PSSS results in the lowest viscosity value for crude A,while CHP results in the lowest viscosity value for crude B.An increase in the loss modulus(G")values was obtained with the addition of PSSS or CHP.
机译:研究了科威特原油样品的流变学特性与美国石油学会的比重(API)、减阻材料和浓度、等温和非等温条件以及混合器速度和频率的关系。流变特性的准确测量和分析对于确定减阻剂和环境条件对原油流动特性和所需泵送功率的影响非常重要。实验采用API值分别为14.81(原油A)、16.33(原油B)和14.09(原油C)的不同井获得的3个原油样品。采用不同浓度的聚丙烯酰胺(PAM)对3种原油样品流变性能的影响。在等温和非等温条件下测量了蜡晶形成的破坏和损耗模量(G“)、粘度和应变的变化。将PAM性能与聚(4-苯乙烯磺酸钠)(PSSS)、十二烷基硫酸钠(SDS)、十六烷基三甲基溴化铵(CTAB)、十六烷基膦胆碱(HTPC)和热电联产(PSSS、CTAB和HTPC等摩尔比混合物)的PAM性能进行了比较。当表面活性剂浓度为70 ppm时,PSSS对粗A的粘度值最低,而CHP对粗B的粘度值最低。

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