The 6a10 and 6b10 vibronic bands in the 12A2-12B2 electronic transition of the emission spectra of the benzyl radical obtained using a high resolution Fourier transform spectrometer are rotationally analyzed. The observed rotational contours were fitted by computer simulated rotational contours, providing determination of the variations, ツA, ツB, and ツC of the rotational constants accompanying the vibronic transitions corresponding to each band. The molecular rotational constants A, B, and C are revised for the upper state and for the two lower states, respectively.
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机译:使用高分辨率傅里叶变换光谱仪对苄基自由基发射光谱的12A2-12B2电子跃迁中的6a10和6b10振动带进行了旋转分析。通过计算机模拟的旋转等值线拟合观测到的旋转等值线,从而确定伴随每个波段的振动跃迁的旋转常数的变化 ツA、ツB 和 ツC。分子旋转常数 A、B 和 C 分别针对上级态和两个下级进行了修正。
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