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Infrared absolute intensities of ozone in the 10 and 5 mu m spectral range: New investigations

机译:10 μm 和 5 μ m 光谱范围内臭氧的红外绝对强度:新研究

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Infrared high resolution spectra of ozone O-16(3) have been recorded in the 10 and 5 mu m spectral ranges in order to derive their absolute intensities with a best achievable accuracy. Spectra have been recorded with the home made stepping mode FTS of GSMA (Reims). In the two spectral regions, we use UV-IR crossed beam cell. The quantification of ozone is achieved using UV cross section at 253.65 nm. A check of this UV calibration is also performed using direct pressure measurements of quasi-pure samples of O-3. The intensities are derived from infrared spectra using multifit procedure already tested. In the 10 mu m range, where 12 different spectra have been recorded, 65 well selected lines led to a good agreement (better than 0.3) with the HITRAN 2008 (or 2004) values, confirming our previous work De Backer-Barilly MR, Barbe A. Absolute intensities of the 10 mu m bands of O-16(3). J Mol Spectrosc 305:2001;43-53. In the 5 mu m range, where 18 transitions are selected, we also note a correct agreement with HITRAN 2008, despite a slightly larger averaged value between (1.9) experimental and theoretical (HITRAN). As conclusion, authors suggest the use of current HITRAN 2008 data for atmospheric retrievals.
机译:臭氧O-16(3)的红外高分辨率光谱已记录在10μm和5μm光谱范围内,以便以最佳精度得出其绝对强度。光谱已使用GSMA(兰斯)的自制步进模式FTS记录。在两个光谱区域中,我们使用UV-IR交叉光束单元。臭氧的定量是使用253.65 nm处的紫外横截面实现的。还使用O-3准纯样品的直接压力测量来检查该UV校准。强度是使用已经测试过的多拟合程序从红外光谱得出的。在10μ m范围内,记录了12个不同的光谱,65条精心挑选的谱线与HITRAN 2008(或2004)值具有良好的一致性(优于0.3%),证实了我们之前的工作[De Backer-Barilly MR,Barbe A. O-16(3)的10μ m波段的绝对强度。分子光谱杂志 305:2001;43-53]. 在 5 μ m 范围内,选择了 18 个跃迁,我们还注意到与 HITRAN 2008 的正确一致性,尽管 (1.9%) 实验和理论 (HITRAN) 之间的平均值略大。作为结论,作者建议使用当前的HITRAN 2008数据进行大气反演。

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