Dynamic Light Scattering and FTIR Spectroscopic Investigations on the Reverse Micelles Produced During the Extraction of Nd(III) and Nitric Acid in Tetra Ethylhexyl Diglycolamide

摘要

abstract_textpThe aggregation behaviour of reverse micelles, formed during the extraction of neodymium nitrate and nitric acid, in an organic phase composed of tetra-bis(2-ethylhexyl) diglycolamide (TEHDGA) in n-dodecane (n-DD) was studied, at various temperatures. The organic phase, 0.2M TEHDGA/n-DD was equilibrated with aqueous solutions of nitric acid in the presence and absence of neodymium nitrate. At certain nitric acid and Nd(III) concentration in aqueous phase, the organic phase underwent splitting into two phases, with top phase known as diluent rich phase, the other one known as third phase or metal ion rich phase. Dynamic light scattering, attenuated total reflectance (ATR) -Fourier transform infrared (FTIR) spectroscopy and Raman spectroscopic methods were employed for probing the size and distribution of aggregates present in the organic phase before and after splitting. The investigations revealed that the aggregates, formed in organic phase, interact efficiently with the extracted metal ions and these interactions increased with increase in the concentration of nitric acid and neodymium nitrate in organic phase. In addition, the interaction among the reverse micelles in third phase appear to be very strong as compared to that observed in the organic phase before third phase formation, and such strong interactions resulted in a merger and narrow distribution of reverse micelles in third phase./p/abstract_text