X-ray absorption fine structure determination of the local environment of Er↑(3+) in glass

摘要

Erbium L↑(III)-edge x-ray absorption fine structure (XAFS) and @(4)/13/2 excited state lifetime easurements were performed on aluminosilicate, fluorosilicate, and phosphate glasses with varying erbium concentration. The local erbium environment is shown to be unique in each host In the aluminosilicate, erbium is found to have 6.4 nearest oxygen neighbors at a distance of 2.22 Anstrom and with a Debye-Waller factor of 0.031 Anstrom↓(2). Erbium in the fluorosilicate glass was found to be more highly coordinated with 7.5 nearest neighbor anions. Erbium in the phosphate glass is found to have a smaller disorder factor of 0.021 Anstrom ↓(2) when compared with the silicate glasses. No variation of the environment (3 shells) is observed with changes in rare earth concentration, while the excited state lifetime varies from 1.0 to 9.8 ms in the aluminosilicates, suggesting the absence of erbium clustering at XAFS detectable distances. # 1997 American Institute of Physics. S0003-6951 (97)00705-5