Photoreflectance (PR) spectroscopy has been used to study the surface Fermi level in GaAs by taking account of photovoltaic properties at the semiconductor surface. The PR signal amplitude Verbar;Dgr;R/RVerbar; is proportional to a modulating photovoltageVmgenerated by a modulation light irradiation. To modify the surface potential, the sample was irradiated by a third perturbing light, i.e., a continuous bias lightPb, together with the modulation light. The modulation light power dependence of Verbar;Dgr;R/RVerbar; is extremely sensitive to bias light intensity, surface Fermi level, and temperature. From the analysis of the temperature dependence of Verbar;Dgr;R/RVerbar; on modulationhyphen;light power, the surface Fermi level of 0.47plusmn;0.09 eV below the conduction band was determined for a molecular beam epitaxiallyhyphen;grown GaAs(100).
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