The molecular structure of vinyl chloride has been determined by the technique of gashyphen;phase electron diffraction. The structural parameters, with estimated uncertainties, were found to ber lpar;Cdblbnd;Crpar;thinsp;equals;thinsp;1.355thinsp;lpar;0.008rpar;thinsp;Aring;,r lpar;Csngbnd;Clrpar;equals;1.728thinsp;lpar;0.007rpar;thinsp;Aring;,r lpar;Csngbnd;Hrpar;equals;1.078thinsp;lpar;0.011rpar;thinsp;Aring;, andnCCClequals;121.1deg;thinsp;lpar;0.9deg;rpar;.
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