Anabinitiostudy of complexes involving a chloride ion with one through six water molecules is presented. Calculations are performed using an RHF/6hyphen;31+G(D) theoretical model and partially optimized geometries. Chloridendash;water interaction energies are computed with a correction for basis set superposition. Polarization of the chloride ion by increasing numbers of water molecules causes a decrease from linearity among the energies. For the six water case, deviation from twohyphen;body additivity is approximately 10percnt; of the stabilization energy.
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