首页> 外文期刊>journal of chemical physics >Frustrationhyphen;limited clusters in liquids
【24h】

Frustrationhyphen;limited clusters in liquids

机译:Frustrationhyphen;limited clusters in liquids

获取原文
           

摘要

We present a continuum theory of frustrationhyphen;limited clusters in onehyphen;component glasshyphen;forming liquids that accounts, in part, for the recently reported lsqb;Fischeretal., J. Nonhyphen;Cryst. Solids,131ndash;133, 134 (1991)rsqb;, and quite unexpected, presence in simple glasshyphen;forming liquids of stable clusters at low temperatures (T) and the even less expected persistence for very long times of these clusters at higherTrsquo;s. The model is based on the idea that there is a local structure that is energetically preferred over simple crystalline packing, which is strained (frustrated) over large distances; although in a curved space the preferred packing could lead to lsquo;lsquo;idealrsquo;rsquo; crystallization at temperatures that are usually above the actual freezing temperature, in lsquo;lsquo;flatrsquo;rsquo; space this transition is narrowly avoided. We are led to a newansatzfor theTdependence of the viscosity, which permits us to collapse data for many liquids onto a universal curve.

著录项

获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号