Viscosities of Some Lower Aliphatic Alcohols at Constant Volume

摘要

From an analysis of all the published experimental data for methyl, ethyl,nhyphen;propyl,isobutyl, andnhyphen;octadecyl alcohols, it is shown that, even for these compounds, at constant volume logeegr; is a rectilinear function of 1/Tand the general pattern of behavior is similar to that described previously.Ev, the energy of activation of viscous flow at constant volume, is plotted as a function of volume, and the curve for ethyl alcohol shows an apparently anomalous minimum.