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A recyclable -cyclodextrins-based supramolecular adsorbent for removal of organic dyes

机译:一种可回收的环糊精基超分子吸附剂,用于去除有机染料

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摘要

In this article, a novel recyclable -cyclodextrins (-CDs)-based supramolecular adsorbent had been fabricated. With Fe3O4 magnetic nanoparticles as core, the adsorbent could be separated from water conveniently. Moreover, the hydrophobic -CDs caving had strong host-guest interaction with organic compounds to form complexes. With the pH value changing, the stable complexes would disassemble to recover the adsorbent. Fourier transform infrared analysis, X-ray diffraction measurement, transmission electron microscopy measurements, thermogravimetric analysis, and vibrating sample magnetometer analysis had been explored to confirm the structure and properties of supramolecular adsorbent. Congo red and Rhodamine B were used to characterize the adsorption capacity of adsorbent. By changing the parameters such as temperature, time, adsorbent dosage, and pH value indicated that the designed adsorbent could rapidly remove organic dyes from water with satisfactory removal effects and adsorbent recycling capacity. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45084.
机译:本文制备了一种新型可回收环糊精(-CDs)基超分子吸附剂。以Fe3O4磁性纳米颗粒为核心,可以方便地将吸附剂与水分离。此外,疏水性-CDs崩落与有机化合物具有很强的主客体相互作用,形成络合物。随着pH值的变化,稳定的络合物会分解以回收吸附剂。通过傅里叶变换红外分析、X射线衍射测量、透射电子显微镜测量、热重分析和振动样品磁力计分析等手段对超分子吸附剂的结构和性能进行了验证。刚果红和罗丹明B用于表征吸附剂的吸附能力。通过改变温度、时间、吸附剂用量和pH值等参数,表明所设计的吸附剂能够快速去除水中的有机染料,具有令人满意的去除效果和吸附剂回收能力。(c) 2017 Wiley Periodicals, Inc. J. Appl. Polym.科学 2017, 134, 45084.

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