Multifunctional epoxy resin/polyacrylonitrile-lithium trifluoromethanesulfonate composites films with very high transparency, high dielectric permittivity, breakdown strength and mechanical properties

摘要

Multifunctional transparent composite films with high dielectric permittivity (high-k), breakdown strength, and mechanical properties are urgently required by cutting-edge fields. Herein, novel multifunctional films were facilely prepared through building unique cross-linked structure based on epoxy resin (EP) and polyacrylonitrile (PAN)-lithium trifluoromethane sulfonate (LiTf) complex. Compared with high-k materials reported previously, EP/(PAN-LiTf) films simultaneously show very high transparency, good flexibility, high tensile, and breakdown strengths. For 0.22EP/(PAN-LiTf) film with 22 wt EP, its average transmittance and elongation at break are as high as 91 (600-800 nm) and 12.7, respectively; moreover, its dielectric permittivity, AC breakdown strength and the maximum energy density are severally about 4.9, 1.8, and 15.2 times of those of EP resin, completely overcoming the sticky problems in conductor/polymer composites. The origin behind these attractive properties is intensively discussed, and believed to be attributed to the unique structure of EP/(PAN-LiTf) films. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45218.