Semiclassical Transition Probabilities for Collinear Diatommdash;Diatom Collisions

摘要

The semiclassical model of Heidrich, Wilson, and Rapp is extended to include translationmdash;vibration transition probabilities for the collinear collision of diatomic molecules. The results forH2sngbnd;H2collisions are compared with quantum mechanical results and found to be in good agreement.