For a given misfit we examine the bandhyphen;gap variation of a pseudomorphic overlayer on a thick substrate as a function of substrate orientation. The strain tensor is found to be a strong function of the substrate orientation. For both direct and indirect bandhyphen;gap overlayers, this results in a significant variation in the band gap as the substrate orientation is changed. However, for indirect bandhyphen;gap layers, such as SiGe alloys grown on Si substrates, the change in band gap is accompanied by a lifting of conductionhyphen;bandhyphen;edge degeneracies. The magnitude of this splitting may be as large or larger than the change in the band gap.lz lz lz
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