Radial Limit in the Configurationhyphen;Interaction Method for the 11SState of the Helium Isoelectronic Sequence

摘要

Using the configurationhyphen;interaction method with only radial configurations, precise radial limits are obtained for the ground state of the helium isoelectronic sequence for atomic numbers 1 thru 20. All matrix elements required in the calculation are shown to be obtainable from sums over integers, which eliminates all necessity of any multiple precision arithmetic in the computer calculation. Also, when the atomic number is varied, considerable saving in computer time is achieved by noticing that all Hamiltonian matrix elements are expressible in the formZeegr;A+eegr;2B+eegr;C, whereZis the atomic number, eegr; a nonlinear variational parameter, andA, B,andCare sums independent ofZand eegr;.