Carbon atoms were generated by two photon absorption in carbon suboxide C3O2. Two photon laser induced fluorescence (LIF) excitation spectra using the 3thinsp;3DJprime;larr;2thinsp;3PJPrime;at 287 nm and 4thinsp;1P1larr;2thinsp;1D2at 284 nm transitions were intense showing that LIF is a convenient detection method for carbon atoms in their ground3Pand first excited1Dstates. Calculated values of the relative intensities of the seven allowedJprime;larr;JPrime; transitions were in good agreement with experimental values.
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