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Interatomic potentials for Cd, Zn, and Hg from absorption spectra

机译:Interatomic potentials for Cd, Zn, and Hg from absorption spectra

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The absorption coefficient has been measured over a 65 nm range in the red wing of the 213.8 nm line for Zn vapor at 1000thinsp;deg;C. It has also been measured in the blue wing and over a 60 nm range in the red wing of the 228.7 nm line for Cd vapor at five temperatures between 642 and 955thinsp;deg;C and over a 75 nm range in the red wing of the 253.7 nm line for Hg vapor at five temperatures between 460 and 860thinsp;deg;C. These data are analyzed in terms of the statistical theory of broadening. Oscillator strengths of 1.42plusmn;0.01 and 1.61plusmn;0.06 are obtained for, respectively, the Cd line and the Zn line. Pair potentials for both the ground and lowest excited state are also obtained in all three cases. For Cd this is done assuming no functional form and then assuming Lennardhyphen;Jones potentials. Both methods agree and give a ground state minimum of minus;47.5 meV at 0.482 nm separation and an excited state minimum of minus;1.06 eV at 0.410 nm. A functional form is required for the less extensive Zn data and the Lennardhyphen;Jones form leads to a range of possibilities including ground and excited state minima of minus;56 meV at 0.400 nm and minus;1.30 eV at 0.330 nm, respectively, which are in fair agreement with the theoretical calculations. For Hg the experiments indicate a single excited state and a ground state with a minimum of minus;55 meV. Assuming no functional form for the pair potentials, taking the excited state as doubly degenerate, and assuming the transition probability from the ground to excited state is onehyphen;sixth of the free atom value gives points along the ground and excited state potentials that join smoothly with other experimental results and agree well with the calculation of Baylis for the ground state.

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