...
首页> 外文期刊>journal of chemical physics >Entropy of a quantum squarehyphen;well potential gas at low temperatures
【24h】

Entropy of a quantum squarehyphen;well potential gas at low temperatures

机译:Entropy of a quantum squarehyphen;well potential gas at low temperatures

获取原文

摘要

We calculate the quantum second virial coefficients and their contributions to the canonical entropy for twohyphen; and threehyphen;dimensional systems interacting with a hardhyphen;core squarehyphen;well potential. This provides three examples of quantum mechanical systems in which the canonical entropy becomes greater than the canonical entropy for the corresponding ideal (noninteracting) systems over a finite temperature interval when Boltzmann statistics is assumed, thus contradicting the conjecture of Baierlein. In addition, low temperature expansions of the second virial coefficient and its contributions to the canonical entropy are made for the general threehyphen;dimensional system in powers of the (reduced) temperature.

著录项

获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号