...
首页> 外文期刊>journal of chemical physics >The statistical mechanics of the electrical double layer: Stress tensor and contact conditions
【24h】

The statistical mechanics of the electrical double layer: Stress tensor and contact conditions

机译:The statistical mechanics of the electrical double layer: Stress tensor and contact conditions

获取原文
           

摘要

The aim of this paper is twofold: (i) to clarify the definition of the mechanical (hydrostatic) stress tensor and the Maxwell (electrostatic) stress tensor in nonuniform electrolytes or Coulombic systems, and (ii) to derive contact conditions for an electrolyte at a charged hard wall to include (a) ion size effects, (b) imaging effects at the wall, and (c) effects due to the molecular nature of the solvent (the civilized model). The last result is valid for a general nonlinear dielectric whose molecules can have any electrostatic multipole interactions.

著录项

获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号