Infrared gas phase intensity measurements, polar tensors, and effective charges of vinylidene fluoride and its deuterated modifications

摘要

All gas phase fundamental vibrational intensities for vinylidene fluoride and its deuterated modifications have been measured. Isotopic invariance,Gsum rule, and quantum chemical information have been used in selecting preferred experimental values for the dipole moment derivatives and polar tensor elements of these molecules. The values of these intensity parameters are compared with those found for other molecules. The experimental values are interpreted in terms of electronic charge distortions occurring in these molecules for the various vibrations.