A series of computations has been carried out on the ground (3Sgr;minus;g) and first excited state (1Sgr;+g) of Si2(R=4.244a0) both with and without the use of an atomic effective or pseudopotential. A Gaussian doublehyphen;zeta basis set was utilized and partial electronic correlation was introduced into the wave function by means of the generalized valence bond (GVB) approximation. In all cases, the all electron and effective potential computations are in good agreement. The computations indicate that the stability of the ground (3Sgr;minus;g) state is due to the tendency of silicon to prefer the divalents2p2atomic configuration rather than the tetrahedralsp3atomic configuration. In contrast to the C2carbon analog, the first excited (1Sgr;+g) state of Si2is shown to possess a relatively weak pgr; bond.
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