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Relaxation in supercooled liquids: A generalized hydrodynamic description

机译:Relaxation in supercooled liquids: A generalized hydrodynamic description

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We focus on the frequency dependence of the viscosity eegr;(ohgr;), or more specifically, of the retardational complianceJr(ohgr;), for supercooled liquids. We pursue a phenomenological approach which is related to extended hydrodynamics and is of a form compatible with a modendash;mode coupling theory. While many of the transport coefficients entering the analysis are interrelated so as to give the correct temperature and frequency dependences of the observed quantities, an important consequence of the model is the prediction of nonArrhenius behavior for the Maxwell relaxation time tgr;m. Our phenomenological approach suggests a mode coupling picture in which the bilinear modes are lsquo;lsquo;semiconservedrsquo;rsquo;; in turn, the mode coupling analysis gives molecular insights into the empirical transport or relaxation coefficients.

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