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STUDY ON PERFORMANCE OF EGG YOLK-WHITE SUPPORTED CATALYST FOR DENITRATION AND SO2-RESISTAN CE

机译:蛋黄-蛋白负载催化剂脱硝和抗SO2催化剂CE性能研究

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摘要

The effects of metal oxide supported catalysts on denitration and SO2-resistance were investigated. A series of metal oxide supported catalysts were prepared by the method of equal volume impregnation, and the denitration and SO2-resistance of different properties and structural catalysts were studied. The catalysts were characterized by XRD and SEM, and then the mechanism of denitration and SO2-resistance was analyzed. The result showed these: (1)7KHHJJRONX2Ȗ-Al2O3 supported catalyst had well denitration and SO2-resistance, and the denitration efficiency remained around 81 and 72 , respectively; (2) the denitration and SO2-resistance of egg yolk-white/ supported catalyst prepared by alkaline earth metal oxide was poor, the reason was that the insoluble substances were easily formed in the particles and blocked the channel, so the denitration efficiency was reduced; (3) In the catalysts prepared by eighth group of metal oxides, the efficiency of denitration and SO2-resistance of NiO-CuO/Ȗ-Al2O3 was higher than that of CuO/Ȗ-Al2O3. But comprehensive performance of NiO-CuO/Ȗ-Al2O3 was not as good as that of Fe2O3-X2Ȗ-Al2O3, the denitration efficiency of Fe2O3-X2Ȗ-Al2O3 remained around 83 and 79.6, respectively.
机译:研究了金属氧化物负载催化剂对脱硝和耐SO2的影响。采用等体积浸渍法制备了一系列金属氧化物负载催化剂,研究了不同性能和结构催化剂的反硝性和耐SO2性能。采用XRD和SEM对催化剂进行了表征,分析了催化剂的反硝机理和抗SO2性能。结果表明:(1)7KHHJJRON&X2Ȗ-Al2O3负载催化剂具有良好的脱硝性和抗SO2性能,脱硝效率分别保持在81%和72%左右;(2)碱土金属氧化物制备的蛋黄-清/负载型催化剂的反硝性和SO2-resistance性较差,原因是颗粒中易形成不溶性物质并堵塞通道,因此脱硝效率降低;(3)在第八组金属氧化物制备的催化剂中,NiO-CuO/Ȗ-Al2O3的脱硝效率和耐SO2效率均高于CuO/Ȗ-Al2O3。但NiO-CuO/Ȗ-Al2O3的综合性能不如Fe2O3-&X2Ȗ-Al2O3,Fe2O3-&X2Ȗ-Al2O3的脱硝效率分别保持在83%和79.6%左右。

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