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Flame synthesis of graphene films in open environments

机译:开放环境下石墨烯薄膜的火焰合成

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摘要

Few-layer graphene is grown on copper and nickel substrates at high rates using a novel flame synthesis method in open-atmosphere environments. Transmittance and resistance properties of the transferred films are similar to those grown by other methods, but the concentration of oxygen, as assessed by X-ray photoelectron spectroscopy, is actually less than that for graphene grown by chemical vapor deposition under near vacuum conditions. The method involves utilizing a multi-element inverse-diffusion-flame burner, where post-flame species and temperatures are radially-uniform upon deposition at a substrate. Advantages of the specific flame synthesis method are scalability for large-area surface coverage, increased growth rates, high purity and yield, continuous processing, and reduced costs due to efficient use of fuel as both heat source and reagent. Additionally, by adjusting local growth conditions, other carbon nanostructures (i.e. nanotubes) are readily synthesized.
机译:在开放气氛环境中,使用一种新的火焰合成方法在铜和镍衬底上高速生长了几层石墨烯。转移薄膜的透射率和电阻性能与其他方法生长的相似,但通过X射线光电子能谱评估的氧浓度实际上低于在近真空条件下通过化学气相沉积生长的石墨烯。该方法涉及利用多元素逆扩散火焰燃烧器,其中火焰后物质和温度在基板上沉积时呈径向均匀。特定火焰合成方法的优点是可扩展性,可实现大面积表面覆盖,提高生长速率,高纯度和产量,连续加工,以及由于有效使用燃料作为热源和试剂而降低成本。此外,通过调整局部生长条件,可以很容易地合成其他碳纳米结构(即纳米管)。

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