Hydrogen bonding of dimethylphosphate anion (DMP) and dimethyl phosphoric acid (DMPH) with water, methanol, and methylamine was studied using the CNDO/2 molecular orbital method. The computed lengths of Ondash;Hsdot;sdot;sdot;O hydrogen bonds involving the phosphate group were significantly shorter than were the computed values for nonphosphate Ondash;Hsdot;sdot;sdot;O bonds, in agreement with experiment. The lowest energy for the monohydration of DMP or DMPH was obtained for the linear hydrogen bond in which the atoms of water were coplanar with the anionic oxygens of the phosphate group. The hydrogen bond strengths of methanol and water with DMP or DMPH were of comparable magnitude, but the Nndash;Hsdot;sdot;sdot;O bond involving methylamine and DMP was about 25percnt; weaker. The Cndash;Hsdot;sdot;sdot;O interaction between the methyl group of methanol or methylamine and the phosphoryl oxygen was also examined and found to have all the characteristics (bond strength, charge transfer, and atomic polarization) of a hydrogen bond. The computed bond strength for HOCH3sdot;sdot;sdot;DMP was minus;7.1 kcal/mole, as compared to minus;21.8 kcal/mole for a conventional CH3OHsdot;sdot;sdot;DMP hydrogen bonding interaction.
展开▼