Schiffbase complexes of dioxouranium(VI). VII. Dioxouranium(VI) acetate complexes with monobasic bidentate and bibasic tridentateSchiffbases

摘要

1∶1 and 1∶2 molar reactions of dioxouranium(VI) acetate dihydrate with the monobasic bidentateSchiffbases,o-HOC6H4CH=NRoro-HOC10H6CH=NR(R=C2H5,n-C3H7,n-C4H9or C6H5) and bibasic tridentateSchiffbases,o-HOC6H4CH=NR(OH) oro-HOC10H6CH=NR(OH) (R=−CH2CH(CH3)- or —CH2CH2CH2−) have been studied and derivates of the type UO2(OAc)2(SBH), UO2(OAc)2(SBH)2, UO2(OAc)2(SBH2) and UO2(OAc)2(SBH2)2(whereSBHandSBH2represent monobasic bidentate and bibasic tridentateSchiffbase molecules respectively) have been isolated. These have been characterized by elemental analysis, conductance measurements and IR spectra