Going for strain: synthesis of the first 3-iminoazaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

摘要

Reaction of a Li/Cl phosphinidenoid complex with N, N'-dialkyl carbodiimides yielded the novel 3-imino-azaphosphiridine complexes; reaction with water led selectively to the first stable valence isomer of an oxaphosphirane complex.